Valved Cracker Cell for Phosphorus – KPC

Details

  • More than 120 in operation
  • Three-zone temperature concept
  • Fast and precise control over phosphorus flux
  • 100% leak tight all metal metering valve
  • « Zero- burst » patented design
  • Rugged and reliable

Presentation

The Riber valved cracker for phosphorus is designed to provide a safe, simple and highly effective phosphorus source. This multi-zone cell is based upon a patented process to first generate white phosphorus from a commercially available red phosphorus charge and then use this high vapor pressure element to produce very stable P2 fluxes. These fluxes can be quickly and precisely adjusted with very good repeatability, enabling growth of P-containing layers, such as InP, GaInP, GaInAsP…

The valved cracker consists of three main parts: the reservoir, the isolation valve and the cracker stage. The reservoir is made of two sub- assemblies, the evaporator and the condensor.

Working principle

The evaporator is placed inside the condensor and receives the red phosphorus primary loaded charge. For easy loading, the evaporator heated crucible is mounted on an independent base flange. After loading, the red phosphorus is heated to an evaporation temperature to produce P4 that will condense into white phosphorus onto the condenser walls.

The condensor surrounds the red phosphorus evaporator and is connected to the flux valve. An isolation valve vents and pumps down the condensor during re-loading operations. White phosphorus is re-evaporated at a rate dependent upon the condenser temperature, typically 60/100°C, thanks to a thermostatic enclosure allowing independent temperature control of the condensor between 40 and 120°C. The enclosure is heated with a fan assisted forced air circulation and temperature is monitored by a controller.

An all-metal valve is placed between the condensor and the cracker stage. It is fully independent and can easily be serviced or replaced. The micrometer driving mechanism enables fine adjustment and complete interruption of the phosphorus flux to the cracker. The valve is fully leak tight in closed position, enabling cell reloading without venting. The valve is externally heated by a jacket to prevent white phosphorus condensation onto the valve mechanism. KPC 6000 features an additional pneumatic valve dedicated for reloading operations, with very low leak rate

The cracker stage is inserted inside the growth chamber and is connected to the valve. A high conductance transit tube allows the transfer of P4 molecules to the cracking zone. The cracker stage design allows an efficient dissociation of the P4 molecules to P2. The cracker is heated by a flat Ta filament. A WRe thermocouple is used to monitor the cracker stage temperature.

An independent and optional water panel can be provided around the cracker to limit the heat load in the growth chamber.

Caution

Please note that the use of Phosphorus in a MBE reactor requires a phosphorus trap accessory in order to safely use and maintain the reactor, due to phosphorus fire and toxicity hazards. Please consult accessory section or consult Riber for detailed information

Layout


Technical information

Source model KPC250 KPC1200 KPC6000
Filament High purity Ta
Heating filaments Wire Wire (evaporator) + Flat foil (cracker)
Crucible / valve material Al203/Stainless steel
Useful capacity (max load dimensions) 250 cc 1200 cc 6000 cc
Mounting flange (min) CF 40 (2″ 3/4) CF 63 (4.5″) CF 100 (6″)
Valve characteristics
Valve Single Double
Heating mantle – 240 VAC 50 W 180 W 350 W
Open conductance 0.3 l/s 0.36 l/s
Close conductance <5.10-10 l/s
Valve actuator Micrometer valve Micrometer rotating thimble
Typical operating temp 80°C
Max outgassing temperature 150°C heater powered, 250°C heater unpowered, 350°C heater dismounted
Cracker Characteristics
Max outgassing temperature 1300°C
Temperature range/ Operating temperature 400-1200°C / 850-900°C
Power consumption 500W max 1050W max 1500W max
Thermocouple connector C-Type
Temperature stability +/-0.5°C
Reservoir Characteristics
LoadingPort CF63 CF100 CF200
Evaporator max outgassing temperature (empty) 550°C
Evaporator typical operating temperature 350°C
Evaporatormax power consumption 60W max 240W max 300W max
Evaporator thermocouple connector C-type
Condenser max temperature 70°C 120°C
Condenser typical operating temperature 50°C 60°C
Condenser Heater Thermostatic enclosure / 240 VAC / 200 W (KPC250) -400 W (KPC 1200/6000)
Temperature stability +/-0.5°C

Component interfacing

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